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Nuestro Coloquio de Hoy
- To: hinojosa@xxxxxxxxxxx
- Subject: Nuestro Coloquio de Hoy
- From: Guillermo Hinojosa <hinojosa@xxxxxxxxxxx>
- Date: Wed, 24 Feb 2010 11:11:54 -0600
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- Delivery-date: Wed, 24 Feb 2010 11:12:13 -0600
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Estimados Colegas,
En nuestro Coloquio de hoy contaremos con la presencia del Dr. Roland
Lefebvre del Laboratorio de Fotofísica Molecular del CNRS en Orsay,
Francia. Su platica se intitula:
"Zero-Width Resonances and Exceptional Points
in Molecular Photodissociation"
Nos dará mucho gusto contar con su amable presencia, el día de hoy
miércoles 24 de febrero a las 5:30 PM, en el auditorio del Instituto
de Ciencias Físicas de la UNAM- Campus Morelos.
Atentamente:
Maximino Aldana y Guillermo Hinojosa.
~ Abstract ~
The interaction of a molecule with a cw laser field is described by a
time-periodic Hamiltonian. The wave equation has solutions given by the
Floquet formalism, with eigenvalues called the quasi-energies. If the field
can lead to photodissociation of the molecule, these quasi-energies are
complex, with an imaginary part yielding the photofragmention rate. In the
case of intense fields, there is a richness of new processes. We are here
interested[1] by the possibility, with an appropriate choice of laser
intensity, to reduce to zero the imaginary part of the energies of some
of the resonances associated with field-free vibrational states of a
diatomic molecule. The example is the molecular ion H2+. Not all resonances
present this property for a given wavelength. The Floquet formalism is
applicable even for a pulsed laser if the amplitude of the field is varying
smoothly enough. It is then possible to build filtration scenarios where
only the resonances passing through the zero-width phenomenon during the
pulse will survive. Another situation which is possible with an appropriate
choice of both wavelength and intensity is to provoke the coalescence of
two quasi-energies. The corresponding point in parameter plane is called
exceptional. Such points have recently been studied in many areas of physics,
either classical or quantum. They have a number of very important consequences
which will be presented for the case of molecular photodissociation [2].
A condition for two resonances to yield such a point is that they correspond
to respectively a shape-like resonance and a Feshbach-like one. At an
exceptional point the two resonance wave functions merge into a single one,
which is said to be ”self-orthogonal”. With an adiabatic variation
of the parameters along a closed contour around an exceptional point, it is
possible to go from one non-degenerate resonance pole to another. In order to
realize such a transfer, it is necessary to reach a compromise between two
conflicting conditions: the laser pulse must vary slowly enough for an adiabatic
transfer to take place, but fast enough to keep a fair amount of undissociated
molecules. This can be checked through the adiabatic Floquet theory.
[1] O. Atabek, R. Lefebvre, C. Lefebvre and T.T. Ngyugen-Dang,
Phys. Rev. A 74, 063412(2008)
[2] R. Lefebvre, O. Atabek, M. ¢ Sindelka and N. Moiseyev, Phys. Rev. Lett.
103, 123003(2009).